How to handle error for duplicate entries?

Solution:

To check for this specific error, you need to find the error code. It is 1062 for duplicate key. Then use the result from errno() to compare with:

mysqli_query('INSERT INTO ...');
if (mysqli_errno() == 1062) {
    print 'no way!';
}

A note on programming style
You should always seek to avoid the use of magic numbers (I know, I was the one to introduce it in this answer). Instead, you could assign the known error code (1062) to a constant (e.g. MYSQLI_CODE_DUPLICATE_KEY). This will make your code easier to maintain as the condition in the if statement is still readable in a few months when the meaning of 1062 has faded from memory 🙂